TRANSPORT-PROPERTIES OF ANION-EXCHANGE MEMBRANES IN CONTACT WITH HYDROCHLORIC-ACID SOLUTIONS - MEMBRANES FOR ACID RECOVERY BY ELECTRODIALYSIS

被引：30

作者：

BOUDETDUMY, M

LINDHEIMER, A

GAVACH, C

机构：

[1] Laboratory of Physical Chemistry of Polyphasic Systems, CNRS, USTL, 34033 Montpellier Cedex

来源：

JOURNAL OF MEMBRANE SCIENCE | 1991年 / 57卷 / 01期

关键词：

ION-EXCHANGE MEMBRANE; ELECTROCHEMISTRY; ELECTRODIALYSIS; SELEMION MEMBRANE; MORGANE MEMBRANE; CHLORIDE ION TRANSPORT; RADIOTRACER TECHNIQUE;

D O I：

10.1016/S0376-7388(00)81162-X

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The transport numbers of chloride ion as well as unidirectional fluxes under a constant current are measured by the radiotracer technique. The studied anion exchange membranes are in contact on both sides with hydrochloric acid at the same concentration. The membranes are the commercial membranes AAV Selemion and ARA Morgane, specially designed for the recovery of acids by electrodialysis. In addition, measurements of the electrical conductances of the membrane and of the amount of sorbed electrolyte at equilibrium have been carried out. The analysis of the results suggests a low dissociation degree of the acid present in the membrane phase.

引用

页码：57 / 68

页数：12

共 13 条

[1]

BOBRINSKAYA G, 1985, TEOR PRAKT SORPTIONN, V17, P111

[2] SULFURIC-ACID CONCENTRATION WITH AN ELECTRO ELECTRODIALYSIS PROCESS [J].

CHERIF, AT ;

GAVACH, C ;

COHEN, T ;

DAGARD, P ;

ALBERT, L .

HYDROMETALLURGY, 1988, 21 (02) :191-201

[3]

EISENMANN JL, 1979, 2 C ADV POLL CONTR M, P99

[4] DONNAN LAW AND ITS APPLICATION TO ION EXCHANGER POLYMERS [J].

GLUECKAUF, E ;

WATTS, RE .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1962, 268 (1334) :339-&

[5]

GREBENYUK VD, 1986, KHIM TEKHNOL VODY, V8, P76

[6]

GUNJIMA, 1975, Patent No. 76103089

[7]

HANLEY TR, 1985, AICHE S SER, V82, P121

[8] RECOVERY OF SULFURIC-ACID WITH MULTICOMPARTMENT ELECTRODIALYSIS [J].

HUANG, TC ;

JUANG, RS .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1986, 25 (02) :537-542

[9] ELECTRODIALYSIS FOR INDUSTRIAL WATER CLEANUP [J].

LEITZ, FB .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1976, 10 (02) :136-139

[10] A STUDY OF THE SUPERSELECTIVITY OF NAFION PERFLUOROSULFONIC MEMBRANES [J].

LINDHEIMER, A ;

MOLENAT, J ;

GAVACH, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 216 (1-2) :71-88

← 1 2 →