MAGNETIC-PROPERTIES OF THE ALTERNATING-CHAIN COMPOUNDS CU(BIPY)X2 (BIPY = 2,2'-BIPYRIDINE, X = BR OR CL)

被引：6

作者：

SPODINE, E

ATRIA, AM

CALVO, V

MANZUR, J

GARLAND, MT

PENA, O

SERGENT, M

机构：

[1] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,SANTIAGO,CHILE

[2] UNIV RENNES 1,CHIM MINERALE LAB B,CNRS,UA 254,CAMPUS BEALIEU,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 10期

关键词：

D O I：

10.1039/dt9910002707

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Magnetic susceptibility data have been collected for the complexes Cu(bipy)X2 (bipy = 2,2'-bipyridine, X = Br or Cl) in the temperature range 2-300 K. The data were analysed in terms of the alternating-chain Heisenberg exchange model to yield J = -0.83 cm-1 and alpha = 0.22 for the chloro complex and J = -1.00 cm-1 and alpha = 0.26 for the bromo complex. This fit is compared with the values obtained by using the Bleaney-Bowers equation for dimeric copper(II) compounds.

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页码：2707 / 2710

页数：4

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