SYNTHESIS AND STRUCTURE OF AN [SB12SE20]4- SALT - THE LARGEST MOLECULAR ZINTL ION

被引：33

作者：

MARTIN, TM ^{[1
]}

WOOD, PT ^{[1
]}

KOLIS, JW ^{[1
]}

机构：

[1] CLEMSON UNIV,DEPT CHEM,CLEMSON,SC 29634

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 08期

关键词：

D O I：

10.1021/ic00086a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first molecular antimony selenide anionic cluster, Sb12Se20(4-), is reported. The compound can be isolated as a PPh4+ salt from the reduction of Sb4Se4 with potassium in DMF. It contains two incomplete cubes connected to opposite sides of a corrugated Sb6Se6 ring by bridging selenides. The arachnid nature of the structure leads to formation of two large voids within the cluster. The cluster may be the largest molecular Zintl ion reported to date.

引用

页码：1587 / 1588

页数：2

共 34 条

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