SYNTHESIS OF VINYLIC SELENIDES AND TELLURIDES BY THE ADDITION OF ALKANESELENOLATE AND ALKANESTELLUROLATE ANIONS TO ACETYLENES

被引：29

作者：

POTAPOV, VA

AMOSOVA, SV

机构：

[1] Institute of Organic Chemistry, Siberian Division of the Russian Academy of Sciences

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 79卷 / 1-4期

关键词：

VINYLIC SELENIDES AND TELLURIDES; ALKANESELENOLATE AND ALKANESTELLUROLATE ANIONS; DIALKYL DISELENIDES AND DITELLURIDES; ACETYLENE; PHENYLACETYLENE;

D O I：

10.1080/10426509308034419

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alkaneselenolate and -tellurolate anions, which are generated from dialkyl dichalcogenides in the system potassium hydroxide-hydrazine hydrate-dimethyl sulfoxide-water, add to acetylene and phenylacetylene to give alkyl vinyl chalcogenides and (Z)-alkyl styryl chalcogenides in high yield.

引用

页码：277 / 280

页数：4

共 12 条

[1]

AMOSOVA SV, 1990, ZH ORG KHIM+, V26, P2224

[2]

AMOSOVA SV, 1990, B IZOBR, V20

[3]

AMOSOVA SV, Patent No. 1567573

[4] VINYLIC SELENIDES [J].

COMASSETO, JV .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 253 (02) :131-181

[5] SYNTHESIS OF VINYLIC TELLURIDES [J].

DABDOUB, MJ ;

DABDOUB, VB ;

COMASSETO, JV ;

PETRAGNANI, N .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 308 (02) :211-222

[6]

GUSAROVA NK, 1988, ZH ORG KHIM+, V24, P1869

[7]

GUSAROVA NK, 1983, ZH ORG KHIM+, V19, P2477

[8]

PAULMIER C, 1986, SELENIUM REAGENTS IN, P182

[9]

POTAPOV VA, 1990, B IZOBR, V20

[10]

POTAPOV VA, Patent No. 1567572

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