COMMENT ON KIRKWOOD INSTABILITY

被引：19

作者：

KUNKIN, W

FRISCH, HL

机构：

[1] Department of Chemistry, State University of New York at Albany, Albany

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 04期

关键词：

D O I：

10.1063/1.1671277

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kirkwood's instability incorrectly predicts a phase transition for hard rods. A reinterpretation, considering a uniform fluid perturbed by a small external force, in the absence of a phase transition is attempted, but is unsuccessful. In some cases, the perturbation results in a mechanically more stable system.

引用

页码：1817 / &