MOLECULAR STRUCTURE OF N-METHYLDISILYLAMINE

被引：65

作者：

GLIDEWELL, C

RANKIN, DWH

ROBIETTE, AG

SHELDRIC.GM

机构：

[1] University Chemical Laboratory, Cambridge, CB2 1EN England, Lensfield Road

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1969年 / 4卷 / 2-4期

关键词：

D O I：

10.1016/0022-2860(69)80056-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular structure of N-methyldisilylamine, (SiH3)2NCH3, in the gas phase has been determined by the sector microphotometer method of electron diffraction. The heavy atoms are coplanar, with a Si-N-Si angle of 125.4 ± 0.4°: the Si-N and C-N bond lengths are 1.726 ± 0.003 Å and 1.465 ± 0.005 Å respectively. These results are compared with those for disilylamine. © 1969.

引用

页码：215 / +

页数：1

共 11 条

[1] EFFECTS OF ANHARMONICITY OF VIBRATION ON THE DIFFRACTION OF ELECTRONS BY FREE MOLECULES
BARTELL, LS
[J]. JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (07) : 1219 - 1222
[2] AN ELECTRON DIFFRACTION STUDY OF GASEOUS DICHLORINE MONIXIDE . RG DISTANCES AND THEIR VIBRATIONAL AMPLITUDES
BEAGLEY, B
CLARK, AH
HEWITT, TG
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (03): : 658 - &
[3] ELECTRON DIFFRACTION STUDY OF MOLECULAR STRUCTURE OF TRISILYLPHOSPHINE
BEAGLEY, B
ROBIETTE, AG
SHELDRICK, GM
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (12): : 3002 - +
[4] ELASTIC ELECTRON SCATTERING AMPLITUDES FOR NEUTRAL ATOMS CALCULATED USING PARTIAL WAVE METHOD AT 10 40 70 AND 100 KV FOR Z=1 TO Z=54
COX, HL
BONHAM, RA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (08) : 2599 - &
[5] CYVIN SJ, 1968, MOLECULAR VIBRATIONS
[6] Derivatives of monosilane Part I The reactions of chlorosilane with aliphatic amines
Emeleus, HJ
Miller, N
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1939, : 819 - 823
[7] GLIDEWELL C, TO BE PUBLISHED
[8] INFRARED STUDIES OF DIMETHYLSILYLAMINE AND METHYLDISILYLAMINE BY MATRIX-ISOLATION TECHNIQUE
GOLDFARB, TD
KHARE, BN
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (09) : 3384 - &
[9] THE MOLECULAR STRUCTURE OF TRISILYLAMINE (SIH3)3N
HEDBERG, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (24) : 6491 - 6492
[10] ELECTRON DIFFRACTION DETERMINATION OF MOLECULAR STRUCTURE OF DISILAZANE
RANKIN, DWH
ROBIETTE, AG
SHELDRIC.GM
SHELDRIC.WS
AYLETT, BJ
ELLIS, IA
MONAGHAN, JJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (08): : 1224 - &

← 1 2 →