CATALYTIC ASYMMETRIC HYDROSILYLATION OF 1,3-DIENES WITH NEW CHIRAL FERROCENYLPHOSPHINE-PALLADIUM COMPLEXES

被引：50

作者：

HAYASHI, T

MATSUMOTO, Y

MORIKAWA, I

ITO, Y

机构：

[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

[2] KYOTO UNIV,DEPT SYNTHET CHEM,KYOTO 606,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 03期

关键词：

D O I：

10.1016/S0957-4166(00)82367-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A palladium catalyst coordinated with optically active ferrocenylmonophosphine ligand containing perfluoroalkyl group on the aminoethyl side chain was found to be highly catalytically active and stereoselective for the asymmetric hydrosilylation of several types of conjugated dienes with trichlorosilane to give optically active allylsilanes of over 60% ee. © 1990.

引用

页码：151 / 154

页数：4

共 6 条

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[2] OPTICALLY-ACTIVE CYCLIC ALLYLSILANES .7. PREPARATION BY ASYMMETRIC HYDROSILYLATION AND ANTI STEREOCHEMISTRY IN SE' REACTIONS
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YAMAMOTO, T
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[J]. TETRAHEDRON LETTERS, 1983, 24 (50) : 5661 - 5664
[3] HAYASHI T, 1985, TETRAHEDRON LETT, V26, P3023, DOI 10.1016/S0040-4039(00)98608-8
[4] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-TRANSITION METAL-COMPLEXES .1. PREPARATION OF CHIRAL FERROCENYLPHOSPHINES
HAYASHI, T
MISE, T
FUKUSHIMA, M
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[5] STEREOCHEMISTRY AND MECHANISM OF ASYMMETRIC ALLYLATION OF ALDEHYDES WITH OPTICALLY-ACTIVE ALLYLSILICONATES
HAYASHI, T
MATSUMOTO, Y
KIYOI, T
ITO, Y
KOHRA, S
TOMINAGA, Y
HOSOMI, A
[J]. TETRAHEDRON LETTERS, 1988, 29 (44) : 5667 - 5670
[6] SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .35. SILAFUNCTIONAL ALPHA,BETA-EPOXY SILANES - TRANSFORMATION INTO ERYTHRO AND THREO 1,2-DIOL SKELETONS AND ITS APPLICATION TO THE SYNTHESIS OF (+/-)-EXO-BREVICOMIN
TAMAO, K
NAKAJO, E
ITO, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (19) : 4412 - 4414

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