SYNTHESES AND X-RAY STRUCTURES OF NOVEL PHENOXO-BRIDGED BINUCLEAR COMPLEXES - BIS(MU-PHENOXO)BIS[BIS(ACETYLACETONATO)CHROMIUM(III)] AND ITS PARA-SUBSTITUTED PHENOXO ANALOGS

被引：10

作者：

NAKAHANADA, M ^{[1
]}

FUJIHARA, T ^{[1
]}

FUYUHIRO, A ^{[1
]}

KAIZAKI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 08期

关键词：

D O I：

10.1021/ic00034a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new versatile synthetic route was developed for a series of novel binuclear chromium(III) complexes bridged by ligands such as 4-X-phenoxo, alkoxo, or hydroxo with an extraordinarily wide range of pK(a) values from 7 to 16. The X-ray structural analyses of the phenoxo and 4-methylphenoxo binuclear complexes revealed the racemic forms. The antiferromagnetism exhibited by the preliminary magnetic susceptibility measurements is discussed in relation to the electronic properties of the bridging ligators.

引用

页码：1315 / 1316

页数：2

共 9 条

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