ASYMMETRIC SELENOMETHOXYLATION OF OLEFINS INVOLVING A CHIRAL C2 SYMMETRICAL ELECTROPHILIC ORGANOSELENIUM REAGENT

被引：76

作者：

DEZIEL, R

GOULET, S

GRENIER, L

BORDELEAU, J

BERNIER, J

机构：

[1] Bio-Méga/Boehringer Ingelheim Research Inc., Laval (Québec) H7S 2G5

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 14期

关键词：

D O I：

10.1021/jo00066a010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new chiral C2 symmetrical organoselenium reagent has been synthesized; this compound, in the presence of methanol, reacts with high facial selectivity with olefins to afford the anti selenomethoxylated adducts in very good yields.

引用

页码：3619 / 3621

页数：3

共 21 条

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