STEREOCHEMISTRY AND STEREOELECTRONICS OF AZINES .3. POLYMORPHISM AND C=N-N=C CONFORMATIONAL ISOMERS OF AZINES - X-RAY CRYSTAL AND AB-INITIO STRUCTURES OF 2 ROTATIONAL ISOMERS OF METHYL (PARA-TOLYL) KETONE AZINE

被引：44

作者：

CHEN, GS ^{[1
]}

ANTHAMATTEN, M ^{[1
]}

BARNES, CL ^{[1
]}

GLASER, R ^{[1
]}

机构：

[1] UNIV MISSOURI,DEPT CHEM,COLUMBIA,MO 65211

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 10期

关键词：

D O I：

10.1002/anie.199410811

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conjugative effects are not significant for the conformation of diaryl‐substituted azines such as 1—whether within the azine unit or between the aryl substituents and the azine or imino units. This was the conclusion of studies of X‐ray crystal structures and quantum chemical calculations. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1081 / 1084

页数：4

共 36 条

[1]

ARTSCHWAGERPERL U, 1989, THESIS RUHR U

[2]

ASANO T, 1973, REV PHYS CHEM JPN, V43, P82

[3] ACTIVATION AND REACTION VOLUMES IN SOLUTION [J].