Tris 1-nitroso-2-naphtholate complex of ruthenium(II): An efficient building unit for polynuclear complexes

被引:44
作者
Das, AK
Rueda, A
Falvello, LR
Peng, SM
Bhattacharya, S [1 ]
机构
[1] Jadavpur Univ, Dept Chem, Inorgan Chem Sect, Calcutta 700032, W Bengal, India
[2] Univ Zaragoza, Fac Sci, Dept Inorgan Chem, E-50009 Zaragoza, Spain
[3] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
关键词
D O I
10.1021/ic990191a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of 1-nitroso-2-naphthol (HL) with ruthenium trichloride afforded the facial isomer of [Ru-II(L)(3)](-) (1), which has been isolated as the triethylammonium salt. Using [Ru-II(L)(3)](-) as a tridentate ligand, a heterometallic trinuclear complex, viz., [{Ru(L)(3)}(2)Ni] (2), has been synthesized.
引用
收藏
页码:4365 / +
页数:5
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