EXCIMER LASER PHOTOLYSIS IN CBR4 AND CF2BR2 - LUMINESCENCE FROM BR2,BR,CF2, AND C2

被引：48

作者：

SAM, CL

YARDLEY, JT

机构：

[1] Corporate Research Center, Allied Chemical Corporation, Morristown

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 61卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)87161-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Primary molecular luminescence arising from excimer laser photolysis of CBr4 and CF2 Br2 has been assigned to Br2 D′ → A′) and CF2 (A≈ → X≈) transitions. For CF2, transitions terminating in ground state levels as high as ν″2 = 27 were measured. Additional emission was observed from Br and from C2. Mechanisms for the photoprocesses are discussed. © 1979.

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页码：509 / 512

页数：4

相关论文

共 18 条

[1] A'3SIGMAG--X'3IIU BAND SYSTEM OF C2 MOLECULE [J].

BALLIK, EA ;

RAMSAY, DA .

ASTROPHYSICAL JOURNAL, 1963, 137 (01) :61-&

[2] AN EXTENSION OF PHILLIPS SYSTEM OF C2 AND A SURVEY OF C2 STATES [J].

BALLIK, EA ;

RAMSAY, DA .

ASTROPHYSICAL JOURNAL, 1963, 137 (01) :84-&

[3] TRANSIENT ABSORPTION SPECTRA OF CHLORINE AND BROMINE [J].

BRIGGS, AG ;

NORRISH, RGW .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1963, 276 (1364) :51-+

[4] COLLISIONLESS PRODUCTION OF C2(API-3U) IN AN INTENSE INFRARED-LASER FIELD [J].

CAMPBELL, JD ;

YU, MH ;

WITTIG, C .

APPLIED PHYSICS LETTERS, 1978, 32 (07) :413-415

[5]

EWING JJ, 1976, TUNABLE LASERS APPLI, P21

[6] MULTI-PHOTON ULTRAVIOLET PHOTOCHEMISTRY [J].

JACKSON, WM ;

HALPERN, JB ;

LIN, CS .

CHEMICAL PHYSICS LETTERS, 1978, 55 (02) :254-258

[7] PRODUCTION OF EXCITED METAL ATOMS BY UV MULTI-PHOTON DISSOCIATION OF METAL ALKYL AND METAL-CARBONYL COMPOUNDS [J].

KARNY, Z ;

NAAMAN, R ;

ZARE, RN .

CHEMICAL PHYSICS LETTERS, 1978, 59 (01) :33-37

[8]

Kiess CC, 1930, BUR STAND J RES, V4, P667

[9]

KODA S, 1978, CHEM PHYS LETT, V55, P353, DOI 10.1016/0009-2614(78)87037-7

[10] ABSORPTION SPECTRUM OF CF [J].

MATHEWS, CW .

CANADIAN JOURNAL OF PHYSICS, 1967, 45 (07) :2355-&