STABILITY OF AS(V) IN CHLORO-COMPOUNDS

被引：6

作者：

DEMIRAY, AF

BROCKNER, W

机构：

[1] Anorganisch-Chemisches Institut, Technische Universität Clausthal, Clausthal-Zellerfeld

来源：

MONATSHEFTE FUR CHEMIE | 1979年 / 110卷 / 04期

关键词：

AsCl[!sub]4[!/sub]SbCl[!sub]6[!/sub; Melt; PCl[!sub]4[!/sub]AsCl[!sub]6[!/sub; PCl[!sub]4[!/sub]SbCl[!sub]6[!/sub; Raman spectra;

D O I：

10.1007/BF00906673

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature dependent behaviour of PCl4AsCl6, PCl4SbCl6 and AsCl4SbCl6 has been investigated by Raman spectroscopy. The As(V) containing complexes decompose into homogeneous molecular melts consisting of AsCl3, Cl2 and PCl5, respectively. In PCl4SbCl6 PCl4+ and SbCl6- complex ions were found in the solid as well as in the molten state. © 1979 Springer-Verlag.

引用

页码：799 / 804

页数：6

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