SYNTHESIS OF CYCLOBUTANONES BY THE PHOTOLYTIC REACTION OF CHROMIUM CARBENE COMPLEXES WITH OLEFINS - INTERMOLECULAR AND INTRAMOLECULAR REACTIONS

被引：106

作者：

SODERBERG, BC ^{[1
]}

HEGEDUS, LS ^{[1
]}

SIERRA, MA ^{[1
]}

机构：

[1] COLORADO STATE UNIV, DEPT CHEM, FT COLLINS, CO 80523 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 11期

关键词：

D O I：

10.1021/ja00167a038

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclobutanones were synthesized in good yield and with a high degree of stereo-and regioselectivity by the photolytic reaction between a variety of chromium alkoxycarbene complexes and olefins. Bicyclic cyclobutanones were synthesized in good yield and with a high degree of stereo-and regioselectivity by the photolysis of chromium alkoxycarbenes having remote double bonds in the alkoxy group. © 1990, American Chemical Society. All rights reserved.

引用

页码：4364 / 4374

页数：11

共 55 条

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