STEREOCHEMISTRY OF METALLOCENES .29. N-FERROCENESULFONYL AMINO ACIDS - NEW CHROMOPHORIC DERIVATIVES OF OPTICALLY ACTIVE ALPHA-AMINO ACIDS

被引:28
作者
FALK, H
KRASA, C
SCHLOGL, K
机构
[1] Organisch-chemischen Institut der Universität Wien, Wien
来源
MONATSHEFTE FUR CHEMIE | 1969年 / 100卷 / 05期
关键词
D O I
10.1007/BF00900170
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Optical rotatory dispersion and circular dichroism of several N-ferrocenesulfonyl-(S)-α-amino acids, as well as of their ethyl esters were recorded. In all cases (with the exception of the proline and hydroxyproline derivatives) the (S)-configuration of the center of chirality was found to correspond with a negative Cotton effect in the region of the ferrocene band" (around 450 nm). © 1969 Springer-Verlag."
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页码:1552 / &
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