HYPER-RAMAN SCATTERING BY CHIRAL MOLECULES

被引:50
作者
ANDREWS, DL
THIRUNAMACHANDRAN, T
机构
[1] Department of Chemistry, University College
关键词
D O I
10.1063/1.437535
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A theory of hyper-Raman scattering by optically active molecules is presented. It is shown that scattering intensities depend on the helicity of the incident light: Expressions for the differential scattering intensities are derived taking into account electric dipole and quadrupole and magnetic dipole interactions. A helical box model is used to estimate circular differential scattering intensity ratios and depolarization ratios. © 1979 American Institute of Physics.
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页码:1027 / 1030
页数:4
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