OPTIMIZATION OF EXPERIMENTAL PARAMETERS FOR THE DETERMINATION OF POLYMER ADDITIVES USING ONLINE SFE-SFC

被引：32

作者：

ASHRAFKHORASSANI, M ^{[1
]}

BOYER, DS ^{[1
]}

LEVY, JM ^{[1
]}

机构：

[1] SUPREX CORP,125 WILLIAM PITT WAY,PITTSBURGH,PA 15238

来源：

JOURNAL OF CHROMATOGRAPHIC SCIENCE | 1991年 / 29卷 / 12期

关键词：

D O I：

10.1093/chromsci/29.12.517

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

An on-line supercritical fluid extraction (SFE) and supercritical fluid chromatographic (SFC) system with a cryofocusing trap is used to analyze quantitatively different additives in polymer matrices. The effects of temperature, matrix configuration, and extraction time are studied. The use of higher temperature shows better extraction efficiency, while matrix configuration experiments demonstrate that better and faster extraction can be obtained as the surface area of the matrix increases.

引用

页码：517 / 521

页数：5

共 15 条

[1] SUPERCRITICAL FLUID EXTRACTION AS A SAMPLE INTRODUCTION METHOD FOR CHROMATOGRAPHY
ANDERSEN, MR
SWANSON, JT
PORTER, NL
RICHTER, BE
[J]. JOURNAL OF CHROMATOGRAPHIC SCIENCE, 1989, 27 (07) : 371 - 377
[2] Ashraf-Khorassani M., 1990, J HIGH RES CHROMATOG, V13, P742
[3] QUALITATIVE SUPERCRITICAL FLUID CHROMATOGRAPHY FOURIER-TRANSFORM INFRARED-SPECTROSCOPY STUDY OF METHYLENE-CHLORIDE AND SUPERCRITICAL CARBON-DIOXIDE EXTRACTS OF DOUBLE-BASE PROPELLANT
ASHRAFKHORASSANI, M
TAYLOR, LT
[J]. ANALYTICAL CHEMISTRY, 1989, 61 (02) : 145 - 148
[4] SEPARATION OF METAL-CONTAINING COMPOUNDS BY SUPERCRITICAL FLUID CHROMATOGRAPHY
ASHRAFKHORASSANI, M
HELLGETH, JW
TAYLOR, LT
[J]. ANALYTICAL CHEMISTRY, 1987, 59 (17) : 2077 - 2081
[5] EVALUATION OF COUPLED SUPERCRITICAL FLUID EXTRACTION-CRYOGENIC COLLECTION-SUPERCRITICAL FLUID CHROMATOGRAPHY (SFE-CC-SFC) FOR QUANTITATIVE AND QUALITATIVE-ANALYSIS
ASHRAFKHORASSANI, M
KUMAR, ML
KOEBLER, DJ
WILLIAMS, GP
[J]. JOURNAL OF CHROMATOGRAPHIC SCIENCE, 1990, 28 (11) : 599 - 604
[6] ASHRAFKHORASSANI M, 1989, J CHROMATOGR SCI, V27, P329
[7] BICKMANN F, 1984, FRESEN Z ANAL CHEM, V319, P305
[8] SUPERCRITICAL FLUID CHROMATOGRAPHIC-SEPARATION OF LOW-POLARITY TO MEDIUM-POLARITY COMPOUNDS THAT ARE DIFFICULT TO ELUTE FROM PACKED-COLUMNS
DOEHL, J
FARBROT, A
GREIBROKK, T
IVERSEN, B
[J]. JOURNAL OF CHROMATOGRAPHY, 1987, 392 : 175 - 184
[9] EXTRACTION OF ANTHRACENE AND BENZO[A]PYRENE FROM SOIL
FOWLIE, PJA
BULMAN, TL
[J]. ANALYTICAL CHEMISTRY, 1986, 58 (04) : 721 - 723
[10] SUPERCRITICAL FLUID CHROMATOGRAPHY
GERE, DR
[J]. SCIENCE, 1983, 222 (4621) : 253 - 259

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