INSITU ACTIVATION OF C(SP3)-S BOND BY TANDEM NICKEL-CATALYZED ALKENATION OF 1-ARYL-1,3-BIS(DITHIOACETALS) WITH ME3SICH2MGCL

被引：13

作者：

WONG, KT ^{[1
]}

LUH, TY ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000564

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aliphatic C-S bond is activated by the in situ generation of a double bond via tandem nickel-catalysed alkenation of 1-aryl-1,3-bisdithioacetals with Me3SiCH2MgCl.

引用

页码：564 / 565

页数：2

共 11 条

[1] NEW DEVELOPMENTS IN PALLADIUM CATALYZED CROSS COUPLING - THE COUPLING OF ALKYL IODIDES WITH ALKYL GRIGNARD-REAGENTS [J].

CASTLE, PL ;

WIDDOWSON, DA .

TETRAHEDRON LETTERS, 1986, 27 (49) :6013-6016

[2] THIOSILANES, A PROMISING CLASS OF REAGENTS FOR SELECTIVE CARBONYL PROTECTION [J].

EVANS, DA ;

TRUESDALE, LK ;

GRIMM, KG ;

NESBITT, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) :5009-5017

[3]

HUET F, 1978, SYNTHESIS-STUTTGART, P63

[4] NICKEL AND PALLADIUM COMPLEX CATALYZED CROSS-COUPLING REACTIONS OF ORGANOMETALLIC REAGENTS WITH ORGANIC HALIDES [J].

KUMADA, M .

PURE AND APPLIED CHEMISTRY, 1980, 52 (03) :669-679

[5] NEW SYNTHETIC APPLICATIONS OF THE DITHIOACETAL FUNCTIONALITY [J].

LUH, TY .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (09) :257-263

[6] A NEW SYNTHETIC ROUTE TO CYCLIC MONO- AND DIKETONE DERIVATIVES VIA BISTHIO CARBANIONS [J].

SEEBACH, D ;

JONES, NR ;

COREY, EJ .

JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (01) :300-&

[7] THE EFFECT OF THE RING SIZE OF THE DITHIOLATO LEAVING GROUP ON THE ORIENTATION OF BETA-ELIMINATION IN THE NICKEL-CATALYZED ALKENATION OF CYCLIC DITHIOACETALS WITH ME3SICH2MGCL [J].

WONG, KT ;

NI, ZJ ;

LUH, TY .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (12) :3113-3116

[8] REGIOSELECTIVE PENTADIENYLATION OF CARBONYL-COMPOUNDS BY OLIGOSILYLATED PENTADIENYLMETALS [J].

YASUDA, H ;

NISHI, T ;

MIYANAGA, S ;

NAKAMURA, A .

ORGANOMETALLICS, 1985, 4 (02) :359-367

[9] ON THE MECHANISM OF THE REDUCTION OF PRIMARY HALIDES WITH GRIGNARD-REAGENTS IN THE PRESENCE OF (DPPF)PDCL2 OR (DPPF)PD(0) [J].

YUAN, K ;

SCOTT, WJ .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (25) :6188-6194

[10] NICKEL-CATALYZED CROSS-COUPLING OF UNACTIVATED NEOPENTYL IODIDES WITH GRIGNARD-REAGENTS [J].

YUAN, KX ;

SCOTT, WJ .

TETRAHEDRON LETTERS, 1991, 32 (02) :189-192

← 1 2 →