SILVER-INDUCED COUPLING OF METHYL 4-BROMOBUT-2-ENOATE

被引：8

作者：

DELLA, EW

KENDALL, M

机构：

[1] School of Physical Sciences, The Flinders University of South Australia, Bedford Park, SA

[2] Department of Chemistry, School of Physical Sciences, La Trobe University, Bundoora, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 11期

关键词：

D O I：

10.1071/CH9692351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of methyl 4-bromobut-2-enoate and silver has been reinvestigated and the coupled product shown to consist of dimethyl octa-trans-2, trans-6-dienedioate (45%), dimethyl 5-vinylhex-trans-2-enedioate (53%), and dimethyl 2,3-dimethylsuccinate (2%). The second constituent is found to undergo isomerization during hydrolysis. None of the isomeric cis-dienes were detected in the coupled product. Coupling does not appear to proceed via free radicals. © 1969, CSIRO. All rights reserved.

引用

页码：2351 / &

共 23 条

[1]

Berner E, 1939, LIEBIGS ANN CHEM, V538, P1

[2] The formation and reactions of iminocompounds Part IX The formation of derivatives of cyclopentane from a delta-dicyano-derivatives of butane [J].