2-METHYLENE-2H-AZIRINES BY PHOTOLYSIS OF 1-AZIDOALLENES

被引：19

作者：

BANERT, K

HAGEDORN, M

机构：

[1] Fachbereich of Organische Chemie, Der Universität‐Gesamthochschule, D-5900, Adolf-Reichwein-Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 01期

关键词：

D O I：

10.1002/anie.199001031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A participation of the resonance structure 2′ is indicated by the 13C‐NMR data of the 2‐methylene‐2H‐azirines 2, which are accessible by photolysis of the 1‐azidoallenes 1. The parent compound 2, R  H, can also be generated photo‐chemically, and can be detected by a trapping reaction in which one equivalent of hydrogen cyanide is added (R  H, Me, CH2OMe, CH2C1). (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

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页码：103 / 105

页数：3

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