COMPLETE DEVELOPMENT OF POLARIZABILITY OF TETRAHEDRAL MOLECULES XY4

被引:7
作者
BOUTAHAR, A
LOETE, M
机构
关键词
D O I
10.1139/p91-005
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A new model of polarizability is presented consistent with the Hamiltonian of tetrahedral molecules XY4. Using a coupling scheme in the T(d) group, polarizability operators are obtained up to any order of approximation for all vibration-rotation bands of any symmetry. This model leads to an unique formula for matrix elements of these operators. We also give the general expression for the Raman intensity of a transition.
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页码:26 / 35
页数:10
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