NOVEL REACTIVITY OF THIOMETALLATES - SYNTHESES AND STRUCTURES OF NEW TRANSITION-METAL SULFIDE CLUSTERS CONTAINING WRU2S6 AND RU2S2(SR)2 CORES

被引：39

作者：

MIZOBE, Y ^{[1
]}

HOSOMIZU, M ^{[1
]}

KAWABATA, J ^{[1
]}

HIDAI, M ^{[1
]}

机构：

[1] UNIV TOKYO,DEPT SYNTHET CHEM,TOKYO 113,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 17期

关键词：

D O I：

10.1039/c39910001226

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [(eta-5-C5Me5)RuCl2]2 with an excess of (NH4)2WS4 in THF at reflux gave [(mu-2-S2){(eta-5-C5Me5)Ru}2(mu-3-S)(mu-2-S)2WS], whereas the analogous treatment of [(eta-5-C5Me5)RuCl(mu-SPr(i))2Ru(eta-5-C5Me5)Cl] with (NH4)2MS4 (M = W, Mo) resulted in the formation of [(eta-5-C5Me5)Ru(mu-S2)(mu-SPr(i))2Ru(eta-5-C5Me5)].

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页码：1226 / 1227

页数：2

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