ESTIMATION OF PERFORMANCE-CHARACTERISTICS OF AN ANALYTICAL METHOD USING THE DATA SET OF THE CALIBRATION EXPERIMENT

被引：174

作者：

RODRIGUEZ, LC ^{[1
]}

CAMPANA, AMG ^{[1
]}

LINARES, CJ ^{[1
]}

CEBA, MR ^{[1
]}

机构：

[1] UNIV GRANADA,FAC SCI,DEPT ANALY CHEM,E-18071 GRANADA,SPAIN

来源：

ANALYTICAL LETTERS | 1993年 / 26卷 / 06期

关键词：

ANALYSIS OF REGRESSION; PERFORMANCE CHARACTERISTICS; CALIBRATION; SPECTROFLUORESCENCE; HPLC;

D O I：

10.1080/00032719308019900

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A model to calculate the analytical sensitivity, limit of detection, limit of determination and precision of a method of instrumental analysis through a data set obtained by calibration experiment using the statistical analysis of linear regression, is proposed. This model has been applied to spectrophotometric, spectrofluorimetric and chromatographic methods. The values obtained are independent of the instrument used and can be applied as a criterion of comparison between different methods proposed for the same analyte. Also, these characteristics have been calculated using the IUPAC suggested model and both results have been compared.

引用

页码：1243 / 1258

页数：16

共 32 条

[1] CALIBRATION IN QUANTITATIVE-ANALYSIS .2. CONFIDENCE-REGIONS FOR THE SAMPLE CONTENT IN THE CASE OF LINEAR CALIBRATION RELATIONS [J].

AGTERDENBOS, J ;

MAESSEN, FJMJ ;

BALKE, J .

ANALYTICA CHIMICA ACTA, 1981, 132 (DEC) :127-137

[2] CALIBRATION IN QUANTITATIVE-ANALYSIS .1. GENERAL-CONSIDERATIONS [J].

AGTERDENBOS, J .

ANALYTICA CHIMICA ACTA, 1979, 108 (JUL) :315-323

[3] A RELATIVE DEVIATION LEAST SQUARES METHOD OF DATA TREATMENT [J].

ANDERSON, KP ;

SNOW, RL .

JOURNAL OF CHEMICAL EDUCATION, 1967, 44 (12) :756-&

[4]

Andres A. Martin, 1990, BIOESTADISTICA CIENC

[5]

[Anonymous], 1978, SPECTROCHIM ACTA B, V33, P242

[6]

[Anonymous], 1987, ANALYST, V112, P199

[7]

[Anonymous], 1980, ANAL CHEM, V52, P2242

[8]

Currie LA, 1968, ANAL CHEM, V40, P587

[9] PROBLEMS OF CALIBRATION IN TRACE, INSITU-MICRO AND SURFACE-ANALYSIS [J].

DANZER, K .

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1990, 337 (07) :794-801

[10]

FLORIAN K, 1990, CHEM PRUM, V40, P196

← 1 2 3 4 →