PHOTOINDUCED ELECTRON-TRANSFER REACTION OF CYCLOPROPANONE ACETALS WITH ARYLMETHYL METHANESULFONATE - GENERATION OF BETA-KETO RADICAL SPECIES AND APPLICATION TO C-C BOND FORMATION

被引：13

作者：

ABE, M ^{[1
]}

OKU, A ^{[1
]}

机构：

[1] KYOTO INST TECHNOL,DEPT CHEM & MAT TECHNOL,SAKYO KU,KYOTO 606,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 14期

关键词：

D O I：

10.1039/c39940001673

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoinduced electron transfer reaction of the cyclopropanone acetals 1 with arylmethyl methanesulfonates 4 or 10 as electron accepters was found to generate a transient pair of radicals, the beta-keto radical 3 and the arylmethyl radical, which underwent a novel carbon-carbon bond formation reaction at the sterically hindered beta-position of the esters.

引用

页码：1673 / 1674

页数：2

共 12 条

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