ELECTRON PARAMAGNETIC RESONANCE OF CUPRIC ACETATE - IRRADIATION-INDUCED SPIN PAIRING

被引：9

作者：

MORTONBLAKE, DA

机构：

[1] Division of Molecular Science, National Physical Laboratory, Teddington

[2] Department of Chemistry, Trinity College, Dublin

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 09期

关键词：

D O I：

10.1021/j100843a032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

X-Irradiated crystals of cupric acetate monohydrate were investigated by epr at 77 and at 4.2°K. At both temperatures prominent spectra of a S = 1/2 species were obtained, indicating that the free spin produced by the irradiation in the ligand had paired with one of the spins in the Cu-Cu pair. Assuming cylindrical symmetry g and A components were evaluated by least-squares calculations on data taken from a single (arbitrary) crystal mounting position, giving g∥ = 2.458 ± 0.002, g⊥ = 2.075 ± 0.002, |A| = 435 ± 10 MHz, |B| ≃ 70 MHz.

引用

页码：2964 / +

页数：1

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