POLYMERIZATION OF BENZYL ALCOHOL IN ANHYDROUS HYDROGEN-FLUORIDE - AN EFFICIENT SYNTHESIS OF POLY(PHENYLENEMETHYLENE)

被引：9

作者：

BANKS, RE ^{[1
]}

FRANCOIS, PY ^{[1
]}

PRESTON, PN ^{[1
]}

机构：

[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

来源：

POLYMER | 1992年 / 33卷 / 18期

关键词：

BENZYL ALCOHOL; POLY(PHENYLENEMETHYLENE); ANHYDROUS HYDROGEN FLUORIDE;

D O I：

10.1016/0032-3861(92)90392-A

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

It has been shown that benzyl alcohol is transformed rapidly and almost quantitatively into poly(phenylenemethylene) by adding it to anhydrous hydrogen fluoride at 16-degrees-C; the product is the so-called 'soluble poly(phenylenemethylene)' with a degree of polymerization of approximately 20. p-Methylbenzyl alcohol has also been oligomerized by a similar procedure. The potential for adaption to industrial-scale use is highlighted.

引用

页码：3974 / 3975

页数：2

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