INSITU GENERATION AND CHARACTERIZATION OF GOLD(I) COMPLEXES FROM K[AUCL4] IN AQUEOUS-SOLUTIONS

被引：12

作者：

ANDERSON, JE

SAWTELLE, SM

机构：

[1] Department of Chemistry, Boston College, Chestnut Hill, MA 02167-3860, New Chemistry Building

来源：

INORGANICA CHIMICA ACTA | 1992年 / 194卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)82659-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A highly reactive gold(I) species, assigned as [AuCl2]-, is electrogenerated and its subsequent chemical reactions with L-cysteine, D-penicillamine and imidazole are monitored by electrochemical methods. By this in situ method, electrochemical data for (L-cysteinato)gold(I) and (D-penicillaminato)gold(I) were determined and compared to relevant gold(I) species. Electrochemical and spectroelectrochemical data for the reduction of [AuCl4]- in water is also presented.

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页码：171 / 177

页数：7

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