USE OF NEW CHIRAL HYDROPHILIC GELS FOR DIRECT RESOLUTION ALPHA-AMINOACIDS BY HIGH-PRESSURE LIQUID-CHROMATOGRAPHY

被引：70

作者：

LEFEBVRE, B ^{[1
]}

AUDEBERT, R ^{[1
]}

QUIVORON, C ^{[1
]}

机构：

[1] UNIV PARIS 06, PHYS CHIM MACROMOLECUL LAB, F-75230 PARIS 05, FRANCE

来源：

JOURNAL OF LIQUID CHROMATOGRAPHY | 1978年 / 1卷 / 06期

关键词：

D O I：

10.1080/01483917808060032

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Total resolution of a-aminoacids was achieved by H P L C using porous gels based on acrylamide grafted with chiral substituents (L-a aminoacids) and complexed with metal ions. We discuss the influence of the structure of the gel (porosity, hydrophilicity and coordination affinity), of the kinetics of the ligand exchange, of the nature of the complexing ion and of the chiral graft. © 1978, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：761 / 774

页数：14

共 38 条

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