SYSTEMATIC LINEAR VARIATION OF ATOMIC EXPECTATION VALUES

被引：24

作者：

COHEN, M ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM,INST ADV STUDIES,JERUSALEM 91000,ISRAEL

来源：

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS | 1979年 / 12卷 / 07期

关键词：

D O I：

10.1088/0022-3700/12/7/001

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The systematic variation of both exact and Hartree-Fock expectation values as asymptotically linear functions of the nuclear charge Z is derived, and the unusually high accuracy of certain Hartree-Fock values explained, by means of Z-dependent perturbation theory, the Hellmann-Feynman theorem and the virial theorem.

引用

页码：L219 / L221

页数：3

共 6 条

[1] SYSTEMATIC BEHAVIOR OF CERTAIN HARTREE-FOCK EXPECTATION VALUES [J].

BOYD, RJ .

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1978, 11 (21) :L655-L658

[2]

Clementi E., 1974, Atomic Data and Nuclear Data Tables, V14, P177, DOI 10.1016/S0092-640X(74)80016-1

[3] AN EXPANSION METHOD FOR CALCULATING ATOMIC PROPERTIES [J].

COHEN, M ;

DALGARNO, A .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1961, 261 (1304) :565-+

[4] A PERTURBATION CALCULATION OF PROPERTIES OF THE HELIUM ISO-ELECTRONIC SEQUENCE [J].

DALGARNO, A ;

STEWART, AL .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1958, 247 (1249) :245-259

[5]

LINDERBERG J, 1960, J MOL SPECTROSC, V5, P1

[6] SCALING PROBLEM, VIRIAL THEOREM, AND CONNECTED RELATIONS IN QUANTUM MECHANICS [J].

LOWDIN, PO .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1959, 3 (01) :46-66

← 1 →