DRAMATIC ENANTIOSELECTIVITY CHANGE IN DIHYDROXYLATION OF OLEFINS WITH CHIRAL AMINE-OSMIUM TETROXIDE COMPLEX

被引:48
作者
TOMIOKA, K
NAKAJIMA, M
KOGA, K
机构
[1] Faculty of Pharmaceutical Sciences, University of Tokyo, Hongo, Bunkyo-ku, Tokyo
关键词
D O I
10.1016/S0040-4039(00)88869-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A slight structural modification of a chiral diamine 1 caused a dramatic change in a sense of enantioselectivity in dihydroxylation of olefins with chiral amine-osmium tetroxide complex. © 1990.
引用
收藏
页码:1741 / 1742
页数:2
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