APPLICATION OF ENANTIOSELECTIVE CAPILLARY GAS-CHROMATOGRAPHY IN LIPASE-CATALYZED TRANSESTERIFICATION REACTIONS IN ORGANIC MEDIA

被引：4

作者：

BORNSCHEUER, U ^{[1
]}

SCHAPOHLER, S ^{[1
]}

SCHEPER, T ^{[1
]}

SCHUGERL, K ^{[1
]}

KONIG, WA ^{[1
]}

机构：

[1] INST ORGAN CHEM,W-2000 HAMBURG 13,GERMANY

来源：

JOURNAL OF CHROMATOGRAPHY | 1992年 / 606卷 / 02期

关键词：

D O I：

10.1016/0021-9673(92)87040-F

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The analysis of enantiomeric excesses of substrate and product during an enantioselective reaction can be performed easily with a chiral stationary phase based on gamma-cyclodextrin. The transesterification of six related allylic alcohols to their corresponding acetates was catalysed by lipase from Pseudomonas cepacia.

引用

页码：288 / 290

页数：3

共 10 条

[1]

BORNSCHEUER U, 1991, TETRAHEDRON-ASYMMETR, V2, P323

[2] RESOLUTION OF (+/-)-TRANS-SOBREROL BY LIPASE PS-CATALYZED TRANSESTERIFICATION AND EFFECTS OF ORGANIC-SOLVENTS ON ENANTIOSELECTIVITY [J].