NERNSTIAN BEHAVIOR OF ZIRCONIA OXYGEN SENSORS INCORPORATING COMPOSITE ELECTRODES

被引：16

作者：

BADWAL, SPS

CIACCHI, FT

HAYLOCK, JW

机构：

[1] CSIRO, Clayton, Aust, CSIRO, Clayton, Aust

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1988年 / 18卷 / 02期

关键词：

ELECTRIC MEASUREMENTS - Impedance - ELECTRODES - Platinum - MEMBRANES - Applications - OXYGEN - ZIRCONIUM AND ALLOYS;

D O I：

10.1007/BF01009269

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The Nernstian behavior of zirconia oxygen sensors incorporating composite electrodes has been described in the low temperature ( less than 600 degree C) range. The composite electrodes consisting of a semi-conducting metal oxide and platinum lower the operating temperature of oxygen sensors to about 300-350 degree C, well below that achievable with conventional metal or metal oxide electrodes. Complex impedance measurements made as a function of Pt/metal oxide ratio show that both the electrode resistance and the time constant go through a minimum when plotted against Pt content in the composite.

引用

页码：232 / 239

页数：8

共 8 条

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