EFFECT OF A PHOSPHORUS BRIDGEHEAD ATOM ON THE LOSS OF NEUTRAL SPECIES IN THE MASS-SPECTRA OF BICYCLOOCTANES

被引：10

作者：

VOORHEES, KJ ^{[1
]}

HILEMAN, FD ^{[1
]}

SMITH, DL ^{[1
]}

机构：

[1] UNIV UTAH,FLAMMABIL RES CTR,SALT LAKE CITY,UT 84112

来源：

ORGANIC MASS SPECTROMETRY | 1979年 / 14卷 / 08期

关键词：

D O I：

10.1002/oms.1210140814

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of a bridgehead phosphorus atom, as both the three (phosphate)and five (phosphate) oxidation states, to influence unique mass spectral neutral losses from a 1‐phosphabicyclo[2.2.2]octane system has been investigated. A conventional neutral loss of formaldehyde was found for the phosphites while a unique loss of ethylene was observed for the phosphate. These losses are discussed in terms of the substituent effects from the 4‐position. Copyright © 1979 John Wiley & Sons, Ltd.

引用

页码：459 / 461

页数：3

共 10 条

[1] NUCLEAR MAGNETIC RESONANCE IN POLYCYCLIC COMPOUNDS .2. LONG-RANGE H1-H1 AND H1-P31 COUPLING IN SOME ADAMANTANE AND BICYCLO[2.2.2]OCTANE DERIVATIVES [J].