THE PREPARATION AND CRYSTAL-STRUCTURE OF A SALT WITH THE [(VO2(O(2)CME))(4)(NO3)] MONOANION

被引：12

作者：

ARROWSMITH, S

DOVE, MFA

LOGAN, N

ANTIPIN, MY

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

[2] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000627

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acetonitrile is oxidised to acetate by vanadium(v) oxide trinitrate in the presence of tetraphenylarsonium chloride and the crystal structure of the main reaction product, (C6H5)(4)As[V4O8(O(2)CMe)4(NO3)] 1, is solved; the anion consists of a tetravanadium(v) crown containing a guest nitrate group in a mu 4 mode.

引用

页码：627 / 627

页数：1

共 7 条

[1]

EINSTEIN FW, 1971, INORG CHEM, V10, P678

[2] SYNTHESIS OF TETRANUCLEAR AND PENTANUCLEAR VANADIUM-OXIDE-CARBOXYLATE AGGREGATES [J].