The coordination polyhedron of the Fe-II ion in the title compound, [Fe(C24H27N7)](PF6)(2), is best described as a trigonal antiprism twisted 6 degrees towards a trigonal prism. The tris[4-(2-pyridyl)-3-aza-3-butenyl]amine ligand coordinates to the metal centre through the three pyridine and three imino N atoms, each set of atoms forming two parallel ideal equilateral triangles; the metal ion is located between these two planes. The average values for the Fe-N-pyridine and the Fe-N-imino bond lengths are 1.981 and 1.950 Angstrom, respectively. The tripodal bridging amine N atom lies on the pseudo ternary axis of the molecule and is situated 3.427 (7) Angstrom from the Fe centre.