SULPHUR-BRIDGED COMPLEXES INVOLVING LIGAND 2,2'-DIMERCAPTODIETHYL SULPHURIDE

被引:17
作者
BARCLAY, GA
MCPARTLI.EM
STEPHENS.NC
机构
[1] School of Chemistry, Macquarie University, Eastwood NSW
[2] Department of Chemistry, University of Sheffield, Sheffiel
[3] School of Chemistry, University of New South Wales, Kensington NSW, 2033
关键词
D O I
10.1071/CH9682669
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ligand 2, 2’-dimercaptodiethyl sulphide has been prepared and complexes formed with divalent Ni, Pd, Pt, Pb, Hg, and Co. In each of these compounds there is a 1: 1 molar ratio of ligand to metal. Spectral, magnetic, and conductivity measurements for the nickel(11) and palladium(11) compounds are consistent with molecular configurations involving four-coordinate, neutral, sulphur-bridged structures. © 1968 CSIRO. All rights reserved.
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页码:2669 / &
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