INFINITE DILUTION ACTIVITY-COEFFICIENT VALUES FROM TOTAL PRESSURE VLE DATA - EFFECT OF EQUATION OF STATE USED

被引：29

作者：

MAHER, PJ ^{[1
]}

SMITH, BD ^{[1
]}

机构：

[1] WASHINGTON UNIV,THERMODYNAM RES LAB,ST LOUIS,MO 63130

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS | 1979年 / 18卷 / 04期

关键词：

D O I：

10.1021/i160072a012

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The accurate determination of the infinite dilution activity coefficient values from binary total-pressure VLE data is demonstrated in conjunction with the Mixon-Gumowski-Carpenter data reduction method. For highly accurate data, the procedure is superior to the method which requires the assumption of a correlation form for GE. The sensitivity of the infinite dilution values to the equation of state used to predict the vapor-phase properties is demonstrated. © 1979, American Chemical Society. All rights reserved.

引用

页码：354 / 357

页数：4

共 11 条

[1] DETERMINATION OF ACTIVITY COEFFICIENTS FROM TOTAL PRESSURE MEASUREMENTS [J].