The phase behavior of ternary polymer blends of poly(styrene-co-acrylic acid) (SAA), poly-(ethylene oxide) (PEO), and poly(methyl methacrylate) (PMMA) was investigated as a function of the acrylic acid content in SAA. The immiscible region was decreased as the acrylic acid content in SAA increases. Six segmental interaction energy densities in the ternary blend were evaluated by combining melting point depression and a more extended binary interaction model.