NUCLEOPHILIC-SUBSTITUTION OF [PT(ETA-5-C5ME5)(CO)X] (X = CL, BR) - ISOLATION OF A RING-SLIPPED INTERMEDIATE

被引：9

作者：

BOAG, NM

QUYOUM, R

RAO, KM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000114

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The toluene mediated reaction of [Pt(eta(5)-C5Me5)(CO)X] (X = Cl, Br) with tertiary phosphines affords the unstable intermediates [Pt(eta(1)-C5Me5)(CO)(PR3)X] which decompose with loss of either CO or halide to give [Pt(eta(5)-C5Me5)(PR3)Br] or [Pt(eta(5)-C5Me5)(PR3)(CO)]1 Cl-.

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页码：114 / 115

页数：2

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