SYNTHESIS OF PHENOLIC SESQUITERPENES VIA OXIDATIVE CLEAVAGE OF BENZOCYCLOALKENOLS

被引：21

作者：

HO, TL ^{[1
]}

YANG, PF ^{[1
]}

机构：

[1] NATL TAIWAN INST TECHNOL,DEPT CHEM,TAIPEI,TAIWAN

来源：

TETRAHEDRON | 1995年 / 51卷 / 01期

关键词：

D O I：

10.1016/0040-4020(94)00942-N

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phenolic sesquiterpenes including sesquichamaenol, 6-(2-hydroxy-4-methylphenyl)-2-methyl-3-beptanone, and curcuphenol methyl ether have been obtained from oxidative cleavage of bicyclic precursors by treatment with acidic hydrogen peroxide in a process which probably parallels a biogenetic step A ketone intermediate for curcudiol has also been acquired in the same manner.

引用

页码：181 / 192

页数：12

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