REACTION ACTIVITY AND SELECTIVITY AS A FUNCTION OF SOLUTION IONIC-STRENGTH IN OCT-1-ENE HYDROFORMYLATION WITH SULFONATED PHOSPHINES

被引：32

作者：

DING, H ^{[1
]}

HANSON, BE ^{[1
]}

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 24期

关键词：

D O I：

10.1039/c39940002747

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Salt concentration has a considerable influence on the activity and selectivity of water-soluble hydroformylation catalysts derived from Rh(acac)(CO)(2) and the sulfonated phosphine, P[C6H4(CH2)(3)C6H4SO3Na](3); addition of Na2SO4 or Na2HPO4 to the catalysts enhances the both the rate and selectivity of the hydroformylation reaction.

引用

页码：2747 / 2748

页数：2

共 20 条

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