NEW PHELLANDRENE DERIVATIVES FROM THE ROOT OIL OF ANGELICA-ARCHANGELICA L

被引：15

作者：

ESCHER, S

KELLER, U

WILLHALM, B

机构：

[1] Firmenich SA, Forschungslaboratorien, Genf

来源：

HELVETICA CHIMICA ACTA | 1979年 / 62卷 / 07期

关键词：

D O I：

10.1002/hlca.19790620703

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New Phellandrene Derivatives from the Root Oil of Angelica archangelica L. 2‐Nitro‐1,5‐p‐menthadiene (5), trans‐ and cis‐6‐nitro‐1(7), 2‐p‐menthadiene (6 and 7), trans‐1(7), 5‐p‐menthadien‐2‐yl acetate (9) and a formal phellandrene derivative, 7‐isopropyl‐5‐methyl‐5‐bicyclo [2.2.2]octen‐2‐one (16), have been identified in the root oil of Angelica archangelica L. Starting from (−)‐(R)‐α‐phellandrene (1) (R)‐5, (4R, 6S)‐6/(4R, 6R)‐7, (2S, 4R)‐9 and (1R, 4R, 7R)‐16 as well as (2S, 4R)‐11, (2R, 4R)‐12 and (2R, 4R)‐10 have been prepared. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：2061 / 2072

页数：12

共 31 条

[1] DIHYDROAROMATIC COMPOUNDS IN DIELS-ALDER REACTION .4. SYNTHESIS OF BICYCLIC KETONES [J].