THE CYCLOBUTENIC WAY TO TRIQUINANES - SYNTHESIS OF (+/-) SILPHINENE

被引：12

作者：

FRANCKNEUMANN, M

MIESCH, M

GROSS, L

机构：

[1] Laboratoire de Chimie Organique Synthétique, associé au CNRS, Institut de Chimie, 67000 Strasbourg, 1, rue Blaise Pascal

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 19期

关键词：

CYCLOBUTENE ESTER; DIQUINANE ALCOHOL; BENZYLATION; SILA-NAZAROV REACTION; SILPHINENE;

D O I：

10.1016/S0040-4039(00)71256-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The easily accessible alcohol 2 is oxidized, after protection, to the allylic alcohol 3. The benzyl ether of this diquinanic alcohol is transformed into the triquinanic precursor 9 of (+/-) Silphinene, using a similar reaction sequence as described previously, but using the opposite epimer.

引用

页码：2135 / 2136

页数：2

共 5 条

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FRANCKNEUMANN, M ;

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[3] TOTAL CYCLOPROPENE SYNTHESIS OF A NATURAL ANGULAR TRIQUINANE, (+/-)-SILPHINENE [J].

FRANCKNEUMANN, M ;

MIESCH, M ;

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TETRAHEDRON LETTERS, 1989, 30 (27) :3533-3536

[4]

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[5]

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