STUDIES ON A NEW CATALYST FOR THE HYDROFORMYLATION OF ALKENES USING C60 AS A LIGAND

被引：20

作者：

CLARIDGE, JB ^{[1
]}

DOUTHWAITE, RE ^{[1
]}

GREEN, MLH ^{[1
]}

LAGO, RM ^{[1
]}

TSANG, SC ^{[1
]}

YORK, APE ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,S PARKS RD,OXFORD OX1 3QR,ENGLAND

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 89卷 / 1-2期

关键词：

C60; HYDROFORMYLATION; RHODIUM; THERMAL STABILITY;

D O I：

10.1016/0304-5102(93)E0328-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

RhH(CO)(C60)(PPh3)2 has been synthesised by reacting the hydroformylation catalyst, RhH (CO) (PPh3)3, with an equimolar amount of C60 in toluene. This compound is an efficient catalyst for the hydroformylation of alkenes to aldehydes at 90-degrees-C. The activity and regio-specificity for the conversion of propene, CO and H-2 to butanal are only slightly lower compared to RhH(CO) (PPh3)3, however, the temperature-programmed decomposition of the RhH(CO) (C60) (PPh3)2 compound in the presence of CO and H-2 shows greater thermal stability than the RhH(CO) (PPh3)3.

引用

页码：113 / 120

页数：8

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