RELIABILITY OF METHODS FOR DETERMINATION OF KINETIC-PARAMETERS FROM THERMOGRAVIMETRY AND DSC MEASUREMENTS

被引：103

作者：

PETROVIC, ZS

ZAVARGO, ZZ

机构：

[1] Faculty of Technology, Novi Sad, Yugosl, Faculty of Technology, Novi Sad, Yugosl

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1986年 / 32卷 / 04期

关键词：

CALORIMETRY - CHEMICAL REACTIONS - Reaction Kinetics - MATHEMATICAL MODELS - Reliability;

D O I：

10.1002/app.1986.070320406

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Both integral and differential methods when applied to simple reaction kinetics produce correct values of the kinetic parameters. Methods requiring assumption of reaction order give results which depend on the accuracy of the guess. If the formulas are simplified, solutions of complex integrals of the results, as in the case of the method of D. W. van Krevelen, partly depend on approximations made.

引用

页码：4353 / 4367

页数：15

共 14 条

[1] KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA .2. [J].