CONVENIENT ONE-POT SYNTHESIS OF 1/2-SANDWICH ETA-CYCLOHEPTATRIENYL AND ETA-TOLUENE DERIVATIVES OF THE METALS TITANIUM AND ZIRCONIUM - CRYSTAL-STRUCTURE OF [ZR(ETA-6-C6H5ME)(PME3)2CL2]

被引：14

作者：

DIAMOND, GM ^{[1
]}

GREEN, MLH ^{[1
]}

WALKER, NM ^{[1
]}

机构：

[1] UNIV OXFORD,S PARKS RD,OXFORD OX1 3QR,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80070-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds [M(eta-7-C7H7)L2Cl] (M = Ti; L2 = (PMe3)2, Me2NCH2CH2NMe2, Me2PCH2CH2PMe2. M = Zr; L2 = Me2NCH2CH2NMe2) and the eta-6-arene derivative [Zr(eta-6-C6H5Me)(PMe3)2Cl2] have been prepared in a one-pot reduction of MCl4 in the presence of L2 and an excess of cycloheptatriene or toluene, respectively. The crystal structure of [Zr(eta-6-C6H5Me)(PMe3)2Cl2] has been determined.

引用

页码：C1 / C4

页数：4

共 9 条

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