PHOTOINDUCED IONIC-CONDUCTIVITY IN POLY[(OMEGA-METHOXY)OLIGO(OXYETHYLENE)METHACRYLATE] DOPED WITH TRIPHENYLMETHANE DERIVATIVES

被引：8

作者：

KUBO, N

KOBAYASHI, N

HIROHASHI, R

机构：

[1] CHIBA UNIV,DEPT IMAGE SCI,CHIBA 260,JAPAN

[2] CHIBA UNIV,GRAD SCH SCI & TECHNOL,CHIBA 260,JAPAN

来源：

POLYMER BULLETIN | 1992年 / 28卷 / 01期

关键词：

D O I：

10.1007/BF01045640

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The solid film of poly[(omega-methoxy)oligo(oxyethylene) methacrylate] [P(MEO)] doped with malachite green leuco hydroxide (MGLOH) or triphenylmethylalcohol (TPMOH) has been prepared as a new type of solid polymer electrolyte with controllable ionic conductivity upon photoirradiation. The ionic conductivity for P(MEO) film doped with 0.1mol% MGLOH or 0.05mol% TPMOH increased with UV irradiation. This suggests that the photogenerated ions act as conductive carrier in the matrix. In particular, for the TPMOH doped film, the effect of TPMOH content on the ionic conductivity change has been analyzed with the change of glass transition temperature (Tg) upon UV irradiation.

引用

页码：69 / 74

页数：6