ASYMMETRIC-SYNTHESIS OF AMINES USING A CHIRAL, NON-RACEMIC, CYCLIC SULFINAMIDE

被引：12

作者：

HOSE, DRJ

RAYNHAM, T

WILLS, M

机构：

[1] UNIV BATH,SCH CHEM,CLAVERTON DOWN,BATH BA2 7AY,AVON,ENGLAND

[2] ROCHE PROD LTD,WELWYN GARDEN CIT AL7 3AY,HERTS,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(00)80065-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The homochiral cyclic sulphinamide S(S)R-(+)-1 has been employed in the asymmetric synthesis of alpha-methylbenzylamine via the benzylidene sulphinamide R(S)R-(-)-3. Following diastereoselective reduction and hydrolysis S(S)R-(+)-1 can be recycled in one step from the sulphinic acid 6.

引用

页码：2159 / 2162

页数：4

共 26 条

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