NEW RHODIUM COMPLEXES ANCHORED ON MODIFIED USY ZEOLITES - A REMARKABLE EFFECT OF THE SUPPORT ON THE ENANTIOSELECTIVITY OF CATALYTIC-HYDROGENATION OF PROCHIRAL ALKENES

被引：122

作者：

CORMA, A

IGLESIAS, M

DELPINO, C

SANCHEZ, F

机构：

[1] INST QUIM ORGAN,E-28006 MADRID,SPAIN

[2] INST MAT,E-28006 MADRID,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 18期

关键词：

D O I：

10.1039/c39910001253

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rh-complexes with N-based chiral ligands, when anchored on a modified USY-zeolite which contains profuse supermicropores, produce a remarkable increase of enantioselectivity (> 95%) in the hydrogenation of N-acyldehydrophenylalanine derivatives and represent a truly heterogeneous counterpart of the homogeneous organometallic catalysts.

引用

页码：1253 / 1255

页数：3

共 13 条

[1] MASS-SPECTROMETRIC STUDIES SHOW THAT HYDROGEN-DEUTERIUM EXCHANGE PROCESSES PRECEDE THE HYDROGENATION OF THE TITLE COMPOUND [J].