CRYSTALS OF AN ANTIFERROMAGNETIC 1,3-BUTADIYNE COMPARED WITH A FERROMAGNETIC 1,3,5-HEXATRIYNE CARRYING A 4-CHLORO-3-(N-TERT-BUTYL-N-OXYAMINO)PHENYL

被引：17

作者：

INOUE, K ^{[1
]}

IWAMURA, H ^{[1
]}

机构：

[1] UNIV TOKYO,FAC SCI,DEPT CHEM,7-3-1 HONGO,BUNKYO KU,TOKYO 113,JAPAN

来源：

ADVANCED MATERIALS | 1992年 / 4卷 / 12期

关键词：

D O I：

10.1002/adma.19920041207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Persistent organic radicals with a ferromagnetic interaction in the crystalline state are few and far between. One example is crystalline 1,3,5‐hexatriyne carrying a [4‐chloro‐3‐(N‐tert‐butyl‐N‐oxyamino)‐phenyl] substituent at position 1. This has been studied and compared with crystalline 1,3‐butadiyne (see Figure) carrying the same substituent, which, in contrast, exhibits antiferromagnetic interactions at cryogenic temperatures. (Figure Presented.) Copyright © 1992 Verlag GmbH & Co. KGaA, Weinheim

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页码：801 / 803

页数：3

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